SYNTHESIS AND STRUCTURAL STUDIES OF SOME COPPER (II) COMPLEXES OF SUBSTITUTED SALICYLALDEHYDE BENZOYL HYDRAZINE
Keywords:
Band Gap Energy, Copper(II) Complex, Origin Software, Tauc Plot, UV-Visible Spectroscopy, XSBHAbstract
Spectrum investigations were used to synthesize and analyse a copper complex of type [Cu(II).nH2O(XSBH)]. In a variety of cultured human and animal cells, salicylaldehyde benzoyl hydrazine (SBH) is a potent inhibitor of DNA synthesis. When given to animals receiving transplanted fibrosarcoma, its Cu(II) complexes dramatically reduce tumor growth. We synthesized Cu(II) complexes of substituted salicylaldehyde benzoyl hydrazines (XSBH, X = 5-Cl, 3-NO2, 5-Br, 5-CH3) in order to produce more effective anticancer medicines. The chemical route method was employed in the creation of these complexes. The generated metal complexes were characterized using UV-visible spectroscopy to ascertain their chemical composition. The salicylaldehyde benzoyl hydrazine was revealed to participate in the coordination of Cu(II) in solutions by UV-vis spectra. The crucial information for a nanomaterial's employment in optoelectronic devices is its optical characteristics. The band gap energy is one of the parameters that affect a material's optical characteristics. Three steps can be taken to determine the band gap energy value from experimental UV-Vis absorbance spectrum data: smoothing the curve, determining the value of the baseline arrangement data, and calculating the band gap energy using the Tauc plot method built into the Origin software. We used the experimental UV-Vis absorbance spectra of the materials as input data. Our method yielded estimated band energy of 1.60 eV.
References
M. MOHAN, A. KUMAR, M. KUMAR, Synthesis and Characterization and Antitumor Activity of Manganese (II), Cobalt (II), Nickel (II), Copper (II), Zinc (II) and Platinum (II) Complexes 136 (1987) 65-74.
N. M. Samus et al., Coordination Compounds of Copper (II) 73 (2003) 1611-1615.
M. Mohan et al., Synthesis, Characterization and Antitumor Properties of Some Metal Complexes 31 (1987) 7-26.
Xu H, Yin L, Liu C, Sheng X and ZhaoN 2018 Adv. Mater. 30 1800156
CongxinX and JingboL 2016 J. Semicond. 37(5)051001-1
Choundury K R, So F and Kafafi Z 2011 Compreh. NanoSci. And Tech. 4 183
DAVID K. JOHNSON, TERRANCE B. MURPHY, NORMAN J. ROSE, DNA Synthesis in Cultured Rodent and Human Cells by Aroylhydrazones and by a Copper (II) Complex.
V. Mursyalaat, V. I. Variani, W. O. S.Arsyad, and M. Z. Firihu 2023 J. Phys Conf. Ser: Physics and Its Applications 2498 012042.
N.H. Abd. Raof, S.S. Ng, H. Abu Hassan, Z. Hassan, The Study of Energy Band Gap of Alloys using UV-VIS Spectroscopy 176 (2009) 176-180.
W. Macyk, How to Correctly Determine the Band Gap Energy of Modified Semiconductor Photocatalysts Based on UV−Vis Spectra 9 (2018) 6814-6817.
Rahmi Dewi, Krisman, Zulkarnain, Rahmawati 2019 Characterization of Optical Properties of Thin Film AIP Conf. Proc. 2169, 060002.
Yi-Heng Lu, Yu-Wei Lu, Cheng-Li Wu, UV–visible spectroscopic study of the salicyladehyde benzoylhydrazone and its cobalt complexes 65 (2006) 695–701.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 Sudhir Sawasiya , Pramod Kumar Malviya (Author)

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.